OPTIC ROTATION

PLANE POLARISED LIGHT

This page gives a simple explanation of what plane polarised light is and the way it is affected by optically active compounds.

A simple analogy - "plane polarised string"

Imagine tying a piece of thick string to a hook in a wall, and then shaking the string vigorously. The string will be vibrating in all possible directions - up-and-down, side-to-side, and all the directions in-between - giving it a really complex overall motion.

Now, suppose you passed the string through a vertical slit. The string is a really snug fit in the slit. The only vibrations still happening the other side of the slit will be vertical ones. All the others will have been prevented by the slit.

What emerges from the slit could be described as "plane polarised string", because the vibrations are only in a single (vertical) plane.

Now look at the possibility of putting a second slit on the string. If it is aligned the same way as the first one, the vibrations will still get through.

But if the second slit is at 90° to the first one, the string will stop vibrating entirely to the right of the second slit. The second slit will only let through horizontal vibrations - and there aren't any.

The real thing - plane polarised light

Light is also made up of vibrations - this time, electromagnetic ones. Some materials have the ability to screen out all the vibrations apart from those in one plane and so produce plane polarised light.

The most familiar example of this is the material that Polaroid sunglasses are made of. If you wear one pair of Polaroid sunglasses and hold another pair up in front of them so that the glasses are held vertically rather than horizontally, you'll find that no light gets through - you will just see darkness. This is equivalent to the two slits at right angles in the string analogy. The polaroids are described as being "crossed".

Care!  It is important not to take the analogy too far. The polaroid material doesn't consist of "slits" in any sense of the word. The way it actually polarises the light is quite different (and irrelevant to us here!).

Optically active substances

An optically active substance is one which can rotate the plane of polarisation of plane polarised light. if you shine a beam of polarised monochromatic light (light of only a single frequency - in other words a single colour) through a solution of an optically active substance, when the light emerges, its plane of polarisation is found to have rotated.

The rotation may be either clockwise or anti-clockwise. Assuming the original plane of polarisation was vertical, you might get either of these results.

How can you tell that the plane of polarisation has been rotated?

You use a polarimeter.

The polariser and analyser are both made of polaroid material.

The polarimeter is originally set up with water in the tube. Water isn't optically active - it has no effect on the plane of polarisation. The analyser is rotated until you can't see any light coming through the instrument. The polaroids are then "crossed".

Now you put a solution of an optically active substance into the tube. It rotates the plane of polarisation of the light, and so the analyser won't be at right-angles to it any longer and some light will get through. You would have to rotate the analyser in order to cut the light off again.

You can easily tell whether the plane of polarisation has been rotated clockwise or anti-clockwise, and by how much